1979
DOI: 10.1016/0025-5408(79)90006-0
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Phase relationships in the ambient temperature LixV2O5 system (0.1<x<1.0)

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Cited by 158 publications
(69 citation statements)
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“…[360,846,852±858] Depending on the amount of inserted lithium several structural modifications were observed: a-and e-phases exist for x < 0.01 and 0.35 < x < 0.7 in Li x V 2 O 5 , respectively, exhibiting a V 2 O 5 -type structure with increasing puckering of the layers. [846,852,859,860] For the composition LiV 2 O 5 gliding of one layer out of two leads to the d-phase. [860] These phase transitions are fully reversible and the pristine V 2 O 5 phase is recovered upon lithium deinsertion.…”
Section: Vanadium Oxidesmentioning
confidence: 99%
“…[360,846,852±858] Depending on the amount of inserted lithium several structural modifications were observed: a-and e-phases exist for x < 0.01 and 0.35 < x < 0.7 in Li x V 2 O 5 , respectively, exhibiting a V 2 O 5 -type structure with increasing puckering of the layers. [846,852,859,860] For the composition LiV 2 O 5 gliding of one layer out of two leads to the d-phase. [860] These phase transitions are fully reversible and the pristine V 2 O 5 phase is recovered upon lithium deinsertion.…”
Section: Vanadium Oxidesmentioning
confidence: 99%
“…Originally V 2 O 5 was mostly investigated as electrode material and more than 30 years ago its electrochemical behavior with respect to lithium was already well documented. [ 76 ] Since then, various vanadium oxides were synthesized, and investigated for lithium storage. The most popular include besides V 2 O 5 also VO 2 , V 3 O 8 , V 4 O 10 and V 6 O 13 .…”
Section: Vanadium Oxidesmentioning
confidence: 99%
“…Among a great variety of inorganic materials, transition-metal oxide (TMOs) as CrO 3 was investigated by Armand at Grenoble [20] and transition-metal dichalcogenides (TMDs) were studied by DiSalvo at Bell Laboratories [21], and later by researchers at EXXON [22][23][24][25]. Rechargeable lithium cells using Li-insertion compounds as positive electrodes were developed in the mid 1970s, when Winn and Steele [26,27] at Chloride Technical Ltd reported solid-solution electrode of TiS 2 with lithium and sodium as well, followed by the announcement of Exxon (USA) for its intention to commercialize the Li//TiS 2 system [28]; Bell Laboratories (USA) reported the development of lithium cells constructed with either NbSe 3 or TiS 3 [29], while transition-metal oxides such as V 2 O 5 , V 6 O 13 were investigated by Dickens in the UK [30]. Table 2.1 documents the numerous efforts toward the development of rechargeable lithium batteries using TMOs as positive electrode and Li metal as anode.…”
Section: Historical Overviewmentioning
confidence: 99%