Phase formation in Li2MoO4-K2MoO4-MMoO4 (M = Ca, Pb, Ba) systems and the crystal structure of α-KLiMoO4

Structural Studies and Thermal Analysis in the Cs2MoO4–PbMoO4 System with Elucidation of β-Cs2Pb(MoO4)2

“…The cell parameters increase approximately linearly, while the melting point decreases with increasing ionic radius of the alkali-metal ion. 5 , 6 , 21…”

“… Trends of the cell parameters a , b , and c , volume, and melting point against the ionic radius of the alkali-metal ion with coordination number 10 for A 2 Pb(MoO 4 ) 2 (A = K, Rb, and Cs) using the crystal data from refs ( 5 ), ( 6 ), and ( 21 ) and the ionic radii from ref ( 30 ). The K + values are used as the normalization factor.…”

“…The cell parameters increase approximately linearly, while the melting point decreases with increasing ionic radius of the alkali-metal ion. 5,6,21 Structural Characterization of β-Cs 2 Pb(MoO 4 ) 2 by ND and XRD. The diffraction patterns obtained with neutrons at 773 K and X-rays at 723 K are shown in Figures 6 and 7, respectively, while the refined cell parameters obtained by both methods are listed in Table 2.…”

“…The structural family of binary molybdates and tungstates shows appealing properties, for instance, ferroelastic and ferroelectric behavior. , Among these complex compounds is a group of binary molybdates and tungstates with mono- and bivalent elements, i.e., the A 2 + B 2+ (X 6+ O 4 ) 2 structural type, with A = K, Rb, or Cs, B = Ba and Pb, and X = Mo and W. ,− Moreover, binary molybdates and tungstates are also versatile as host materials for phosphors. , …”

Report of the Double-Molybdate Phase Cs2Ba(MoO4)2 with a Palmierite Structure and Its Thermodynamic Characterization

“…trigonal in space group R3̅ m, and isostructural with K 2 Ba(MoO 4 ) 2 46 and Rb 2 Ba(MoO 4 ) 2 . 47,48 The X-ray and neutron diffraction patterns are shown in parts a and b of Figures 1, respectively. The refined cell parameters obtained from the XRD and ND data are given in Table 1.…”