Abstract:In the present study, phase equilibrium data of the systems (water + orthophosphoric acid + chlorinated methanes) were measured in the temperature range of 298.2−318.2 K under ambient conditions. Chloroform and carbon tetrachloride were chosen as chlorinated solvents. Both the systems exhibited a type II phase behavior. The presence of hydrogen atoms in chloroform caused differences in phase behavior, partition coefficients, and solubility of the acid in the studied chlorinated methanes. Solid orthophosphoric … Show more
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