Phase equilibria of stored chemical energy reactants

Cook, Lawrence P.; Plante, E.R.; Roth, Robert; Hastie, J. W.

doi:10.6028/nbs.ir.84-2940

Cited by 6 publications

(8 citation statements)

References 40 publications

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“…(2) Chlorides may form during initial stages of oxidation 3 (see discussion of kinetics) but are relatively minor phases in the end products.…”

Section: Reaction Productsmentioning

confidence: 99%

“…In our laboratories investigation is continuing of reaction [2a], which is potentially much more complex than as written (2).…”

mentioning

confidence: 99%

“…In addition to reaction [2] LiB/NF, [ 4 ] [5] [ 6 ] [7] [ 8 ] [9] [ 10 ] Combinations [3], [4], and [5] utilize a final stage of combustion in which hydrogen is burned, in a reaction identical to reaction [2b] above.…”

mentioning

confidence: 99%

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Survey of alternate stored chemical energy reactions

Cook¹,

Plante²

1985

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“…(2) Chlorides may form during initial stages of oxidation 3 (see discussion of kinetics) but are relatively minor phases in the end products.…”

Section: Reaction Productsmentioning

confidence: 99%

“…In our laboratories investigation is continuing of reaction [2a], which is potentially much more complex than as written (2).…”

mentioning

confidence: 99%

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Survey of alternate stored chemical energy reactions

Cook¹,

Plante²

1985

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“…It has been suggested that lithium aluminates form at the grain boundaries and act as sintering aids and grain growth aids. 19,36,[39][40][41][42] Work by Jin and McGinn and Wolfenstine, et. al. suggest that at and above the eutectic point of the Li 2 O and Al 2 O 3 phase diagram (1055 C) liquid phase sintering may occur.…”

Section: Introductionmentioning

confidence: 99%

The effects of aluminum concentration on the microstructural and electrochemical properties of lithium lanthanum zirconium oxide

et al. 2022

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“…Thus, a reactive liquid is expected to form slightly below the Li 2 CO 3 melting point when the three reactants in are heated. The formation of lithium aluminates and lithium silicates has been studied previously 14,15 . However, it is not well understood what sequence of reactions are present for the three‐component mixture, as shown in Reaction ().…”

Section: Introductionmentioning

confidence: 99%

Reactions in Eucryptite‐Based Lithium Aluminum Silicates

Jochum

Reimanis

2010

Journal of the American Ceramic Society

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The reaction sequence to synthesize β‐eucryptite, LiAlSiO4, from the raw ingredients SiO2, Li2CO3, and Al2O3 was studied using thermal analysis and X‐ray diffraction techniques. Reactions were examined by heating the raw ingredients as two‐component and three‐component mixtures in air, then cooling for phase analysis. In some cases, cyclic heating was performed to ensure a complete reaction. It was found that a complex sequence of reactions involving several intermediate phases occurs. The single oxides (SiO2 and Al2O3) react with Li2CO3 to form the binary oxides (Li2Si2O5, Li2SiO3, and LiAlO2); SiO2 reacts with Li2CO3 before Al2O3. Subsequently, the binary oxides form ternary oxides (LiAlSi2O6 and LiAlSiO4). Finally, the ternary oxides form the equilibrium product, β‐eucryptite (LiAlSiO4). These reactions are discussed in the context of the thermodynamic properties of the various compounds.

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Phase equilibria of stored chemical energy reactants

Cited by 6 publications

References 40 publications

Survey of alternate stored chemical energy reactions

Survey of alternate stored chemical energy reactions

The effects of aluminum concentration on the microstructural and electrochemical properties of lithium lanthanum zirconium oxide

Reactions in Eucryptite‐Based Lithium Aluminum Silicates

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