Phase diagram of a system of adipic, glutaric, and sebacic acids

Kolyado, A. V.; Alenova, S. M.; Гаркушин, И. К.

doi:10.1134/s0036024416060091

Cited by 10 publications

(1 citation statement)

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“…With the increase of reaction temperature, the organic solvent with a low boiling point evaporates, which makes it difficult to recover the solvent. Thus, the reaction system mobility is poor, and the material is very easy to carbonize, resulting in low yields of sebacic acid (Yabalak et al 2015;Kolyado et al 2016;Perin and Felisberti 2022).…”

Section: Introductionmentioning

confidence: 99%

Optimization of microwave pyrolysis of castor oil to sebacic acid

Yu,

Shen,

et al. 2023

BioRes

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Castor oil is a widely used biomass energy source. In this paper, the process conditions for the preparation of sebacic acid by cracking castor oil using the microwave method were investigated using environmentally friendly and recyclable liquid paraffin (petrolatum) as a solvent. The optimum conditions for the reaction were determined in the experiments as follows: the mass ratio of solvent: castor oil: sodium hydroxide was 4:1:2.5 and the concentration of sodium hydroxide solution was 50% (w/t). The average microwave power was 210 W, the temperature was about 280 °C, the cracking time was 25 min under nitrogen protection, and the yield of sebacic acid was measured to be 85%. The solvents can be recycled and the recovered solvent can be used again without affecting the yield of sebacic acid. The solvent recovery was more than 92%.

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Section: Introductionmentioning

confidence: 99%