Abstract:Inspired by experimental work on colloidal cuboid-polymer dispersions (Rossi et al., Soft Matter, 7, 4139 (2011)) we have theoretically studied the phase behaviour of such mixtures. To that end, free volume theory (FVT) was applied to predict the phase behaviour of mixtures of superballs and nonadsorbing polymer chains in a common solvent. Closed expressions for the thermodynamic properties of a suspension of hard colloidal superballs have been derived, accounting for fluid (F), face-centred cubic (FCC) and s… Show more
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