Phase Behaviour of Binary Hard-Sphere Mixtures: Free Volume Theory Including Reservoir Hard-Core Interactions
J. Opdam,
M. P. M. Schelling,
R. Tuinier
Abstract:Comprehensive calculations were performed to predict the phase behaviour of large spherical colloids mixed with small spherical colloids that act as depletant. To this end, the free volume theory (FVT) of Lekkerkerker et al. [Europhys. Lett. 20 (1992) 559] is used as a basis and is extended to explicitly include the hard-sphere character of colloidal depletants into the expression for the free volume fraction. Taking the excluded volume of the depletants into account in both the system and the reservoir prov… Show more
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