Ph3P/ICH2CH2I-promoted reductive deoxygenation of alcohols

Tang, Wei-Ying; Zheng, Xing; Yao, Xu; Lin, Jin-Hong; Zheng, Qu-Tong; Xiao, Ji-Chang

doi:10.1039/d3ob01698f

Org. Biomol. Chem.

2023

DOI: 10.1039/d3ob01698f

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Ph₃P/ICH₂CH₂I-promoted reductive deoxygenation of alcohols

Wei-Ying Tang,

Xing Zheng,

Xu Yao

et al.

Abstract: Described herein is the Ph3P/ICH2CH2I-promoted reductive deoxygenation of alcohols with NaBH4. A wide substrate scope and good functional group tolerance were observed.

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Ph₃P═O-Catalyzed Reductive Deoxygenation of Alcohols

Li,

Sun,

et al. 2024

J. Org. Chem.

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Reductive deoxygenation of alcohols is particularly challenging because of the high bond dissociation energy of the C−OH bond and the poor leaving ability of the hydroxyl group. Herein we describe a Ph 3 P�O-catalyzed reductive deoxygenation of benzyl alcohols with PhSiH 3 under an air atmosphere within 30 min of reaction time. The use of catalytic loading of Ph 3 P�O enhances the practicality of this protocol.

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Ph₃P═O-Catalyzed Reductive Deoxygenation of Alcohols

Li,

Sun,

et al. 2024

J. Org. Chem.

View full text Add to dashboard Cite

show abstract

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Ph₃P/ICH₂CH₂I-promoted reductive deoxygenation of alcohols

Abstract: Described herein is the Ph3P/ICH2CH2I-promoted reductive deoxygenation of alcohols with NaBH4. A wide substrate scope and good functional group tolerance were observed.

Cited by 1 publication

References 43 publications

Ph₃P═O-Catalyzed Reductive Deoxygenation of Alcohols

Ph₃P═O-Catalyzed Reductive Deoxygenation of Alcohols

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Ph3P/ICH2CH2I-promoted reductive deoxygenation of alcohols

Abstract: Described herein is the Ph3P/ICH2CH2I-promoted reductive deoxygenation of alcohols with NaBH4. A wide substrate scope and good functional group tolerance were observed.

Cited by 1 publication

References 43 publications

Ph3P═O-Catalyzed Reductive Deoxygenation of Alcohols

Ph3P═O-Catalyzed Reductive Deoxygenation of Alcohols

Contact Info

Product

Resources

About

Ph₃P/ICH₂CH₂I-promoted reductive deoxygenation of alcohols

Ph₃P═O-Catalyzed Reductive Deoxygenation of Alcohols

Ph₃P═O-Catalyzed Reductive Deoxygenation of Alcohols