This study reports the analysis of gases evolved during controlled pyrolysis and combustion of cowdung. The combined thermogravimetric (TG)/ Fourtier transform infrared (FTIR)/ mass spectrometry (MS) were employed to analyze the evolved gaseous products. The results revealed that the thermal decomposition of cow-dung occurs in three steps assigned to drying of the sample, fast thermal decomposition and further cracking. The complete combustion of cow-dung occurs at 500°C, while during pyrolysis the total weight loss of 58.91 wt.% was found at 950°C. The release of gaseous product during pyrolysis was CO 2 , CO, methanol, formaldehyde, formic acid, acetic acid, whereas the products during combustion were CO 2 , CO. Among them, CO 2 was the dominant gaseous product in the whole combustion process.