The article researches the effect of five cycles of heating to a temperature of 1000 °C and two cycles of heating to a temperature of 1100 °C on the structure of a layered composite material consisted of 100 alternating layers of 08kp and 08Kh18N10 steels (one layer thickness is ~22 μm). As a result of the nickel and chromium diffusion during thermocycling, the thickness of the layers changed and an interlayer with a structure different from the structure of neighboring layers was formed. Heating to 1100 °C also has led to a partial disarrangement of the layered material structure. It was found that the real diffusion path of alloying elements during heat treatment significantly exceeds the calculated one, and chromium atoms are redistributed between the layers of the material much more actively than nickel atoms.