Abstract. Fine particulate matter (PM2.5) pollution is still one of China's most important environmental issues, especially in northern cities
during wintertime. In this study, intensive real-time measurement campaigns
were conducted in Xi'an, Shijiazhuang, and Beijing to investigate the
chemical characteristics and source contributions of PM2.5 and explore
the formation of heavy pollution for policy implications. The chemical
compositions of PM2.5 in the three cities were all dominated by organic
aerosol (OA) and nitrate (NO3-). Results of source apportionment
analyzed by a hybrid environmental receptor model (HERM) showed that the
secondary formation source contributed more to PM2.5 compared to
other primary sources. Biomass burning was the dominant primary source in
the three pilot cities. The contribution of coal combustion to PM2.5 is
non-negligible in Xi'an and Shijiazhuang but is no longer an important
contributor in the capital city of Beijing due to the execution of a strict
coal-banning policy. The potential formation mechanisms of secondary aerosol in the three cities were further explored by establishing the correlations between the secondary formation sources and aerosol liquid water content (ALWC) and Ox (O3+NO2), respectively. The results showed
that photochemical oxidation and aqueous-phase reaction were two important
pathways of secondary aerosol formation. According to source variations,
air pollution events that occurred in campaigns were classified into three
types: biomass-combustion-dominated, secondary-formation-source-dominated,
and a combination of primary and secondary sources. Additionally, this study
compares the changes in chemical composition and source contributions of
PM2.5 in past decades. The results suggest that the clean-energy
replacements for rural households should be urgently encouraged to reduce the
primary source emissions in northern China, and collaborative control on
ozone and particulate matter needs to be continuously promoted to weaken the
atmosphere oxidation capacity for the sake of reducing secondary aerosol
formation.