2015
DOI: 10.1002/adma.201501959
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Perovskite Sr‐Doped LaCrO3 as a New p‐Type Transparent Conducting Oxide

Abstract: Epitaxial La1-x Srx CrO3 deposited on SrTiO3 (001) is shown to be a p-type transparent conducting oxide with competitive figures of merit and a cubic perovskite structure, facilitating integration into oxide electronics. Holes in the Cr 3d t2g bands play a critical role in enhancing p-type conductivity, while transparency to visible light is maintained because low-lying d-d transitions arising from hole doping are dipole forbidden.

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Cited by 169 publications
(179 citation statements)
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References 44 publications
(61 reference statements)
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“…Generally, semiconducting behavior is observed for most p-type TCs such as delafossites (7,8,18), layered oxychalcogenides (12), and perovskite Sr-doped LaCrO 3 (19), which show thermally activated conductivity near room temperature and variablerange hopping at low temperatures due to the strong localization of carriers. In contrast, the transport properties of the p-type CuI thin films reported here are quite unusual, as can be seen from the temperature (T) dependence of the conductivity (σ) in Fig.…”
Section: Resultsmentioning
confidence: 99%
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“…Generally, semiconducting behavior is observed for most p-type TCs such as delafossites (7,8,18), layered oxychalcogenides (12), and perovskite Sr-doped LaCrO 3 (19), which show thermally activated conductivity near room temperature and variablerange hopping at low temperatures due to the strong localization of carriers. In contrast, the transport properties of the p-type CuI thin films reported here are quite unusual, as can be seen from the temperature (T) dependence of the conductivity (σ) in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…A larger value of FOM indicates better performance of the TC. Due to the absent R values in most studies, the FOM is usually simplified by the approximation R = 0 and using FOM ∼ −1/(R s lnT vis ) (19). As shown in Fig.…”
Section: Resultsmentioning
confidence: 99%
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“…In related work cationic and anion substitution and the role of Cr vacancies in this material has been studied. [66,67] High conductivity has also been shown experimentally in non-Cu metal oxides, most notably spinel-structured TCOs, such as NiCo 2 O 4 , [68,69] perovskites-structured TCOs, such as SrIn x Ti 1-x O 3 and Sr x La 1-x CrO 3 , [70,71] and amorphous or composite oxides, such as ZnO·Rh 2 O 3 and In:MoO 3 . [72,73] Other oxides, such as doped Cr 2 O 3 and Ba 2 BiTaO 6 , have promise but remain to be synthesized with high conductivities.…”
Section: P-type Transparent Conductorsmentioning
confidence: 88%