2021
DOI: 10.1007/s42452-021-04182-7
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Performance-tuning of PVA-based gel electrolytes by acid/PVA ratio and PVA molecular weight

Abstract: The significant breakthroughs of flexible gel electrolytes have attracted extensive attention in modern wearable electronic gadgets. The lack of all-around high-performing gels limits the advantages of such devices for practical applications. To this end, developing a multi-functional gel architecture with superior ionic conductivity while enjoying good mechanical flexibility is a bottleneck to overcome. Herein, an architecturally engineered gel, based on PVA and H3PO4 with different molecular weights of PVA f… Show more

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Cited by 28 publications
(35 citation statements)
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“…Thus, encapsulating the cells is needed to maintain the cell's performance and possibly extend the lifetime of the cells in practical usage. [49][50][51][52] Regardless, our obtained data confirmed the stretching and washing sustainability of our composites as the supercapacitor electrode material. Finally, further research on washable electrolytes would be useful in realizing practical applications of washable supercapacitor applications.…”
Section: Discussionsupporting
confidence: 80%
“…Thus, encapsulating the cells is needed to maintain the cell's performance and possibly extend the lifetime of the cells in practical usage. [49][50][51][52] Regardless, our obtained data confirmed the stretching and washing sustainability of our composites as the supercapacitor electrode material. Finally, further research on washable electrolytes would be useful in realizing practical applications of washable supercapacitor applications.…”
Section: Discussionsupporting
confidence: 80%
“…Before being used, the prepared electrolyte was cooled down to room temperature. The ionic conductivity of the gel electrolyte is estimated to be 0.14 S cm -1 at a viscosity of 0.6×10 5 Pa s. [71,72] The supercapacitor was manufactured in a symmetric configuration, i.e., with two identical electrodes. Prior to assembly, the MPNCelectrodes were immersed into the as-prepared electrolyte for at least 15 min to ensure its infiltration into the pores of the 3D electrode and each MPNC particle.…”
Section: Methodsmentioning
confidence: 99%
“…Before being used, the prepared electrolyte was cooled down to room temperature. The ionic conductivity of the gel electrolyte is estimated to be 0.14 S cm –1 at a viscosity of 0.6×10 5 Pa s. [ 71,72 ]…”
Section: Methodsmentioning
confidence: 99%
“…For PVA/H 3 PO 4 hydrogels with identical PVA fractions, high-molecular-weight (1 95 000) PVA afforded lower conductivity than low-molecular-weight (27 000) PVA. 8 The decreased conductivity was attributed to lower segmental motion of the high-molecular-weight PVA chains, which hindered the diffusion of ions in the hydrogel. In comparison, the polymer fraction had a more profound impact on the conductivity of acid hydrogels.…”
Section: Introductionmentioning
confidence: 99%