PUBLIC ABSTRACTGiven that fossil fuel fired power plants are among the largest and most concentrated producers of CO 2 emissions, recovery and sequestration of CO 2 from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO 2 emissions.In 2001, ALSTOM began a two-phase program to investigate the feasibility of various carbon capture technologies. This program is sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory.Phase I entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO 2 capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represent coal combustion cases in CFB type equipment. Four cases represent Integrated Gasification Combined Cycle (IGCC) systems. Two cases represent advanced Chemical Looping systems. Details of this work have been reported by Marion, et al, (2003).One of the cases studied was the oxygen-fired circulating fluidized bed (CFB) concept. When fired with oxygen, the flue gas from the CFB contains over 70% CO 2 . This flue gas can be processed to produce over 90% CO 2 for sequestration or use in enhanced oil recovery (EOR). The Phase I study identified the O 2 -fired CFB as having a near term development potential.Phase II -which is the subject of this report -consisted of pilot-scale testing followed by a refined performance and economic evaluation of the oxygen-fired CFB concept. As a part of this workscope, ALSTOM modified its 9.9 MM-Btu/hr Multiuse Test Facility (MTF) pilot plant to operate with O 2 /CO 2 mixtures of up to 70 % O 2 by volume. Tests with coal and petroleum coke were conducted. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data was used to refine the design, performance, costs, and economic models developed in Phase-I for an O 2 -fired CFB with CO 2 capture.Key results from the MTF testing are summarized below.• The furnace was successfully operated on bituminous coal and petcoke in O 2 /CO 2 combustion mediums containing local oxygen enrichments of up to 70%. There was no evidence of particle agglomeration or defluidization in the furnace.• Because of the high CO 2 content of the flue gas, the furnace operated above 1650°F to ensure calcination of the limestone for sulfur capture. In regions where the temperature was much cooler, there was evidence of recarbonation.• Because of the high temperature, the sulfur emissions from the bituminous coal were higher than normal for the same limestone feed rate. For pet coke, the optimum temperature for sulfur capture is higher, so the oxygen-fired emissions were very low.• NO x emissions were lower with oxygen firing. This is due to the reduction in prompt NO x , and perhaps some reduction in thermal NO x and fuel NO x ....