The
direct carbon solid oxide fuel cell (DC-SOFC) is a potential
energy conversion device that cleanly and effectively utilizes various
carbon resources to generate electric power through electrochemical
conversion. Recently, DC-SOFCs utilizing real-world coal fuel have
gained great momentum due to the “dual carbon strategic goals”.
Here, we report high-performance La0.9Sr0.1Ga0.8Mg0.2O3‑δ (LSGM) electrolyte-supported
DC-SOFCs, by integrating Ag–Gd0.1Ce0.9O2−δ (GDC) as symmetrical electrodes, which
enable highly efficient utilization of raw brown coal as fuel. As
a comparison, the performances of the conventional yttria-stabilized
zirconia (YSZ) electrolyte supported-DC-SOFCs are also investigated.
Fueled by raw brown coal, the LSGM-based cells can deliver a maximum
power density of 367 mW cm–2 at 850 °C, which
is distinctly superior than that of the YSZ-based cells (249 mW cm–2). In addition, stability tests reveal that under
a discharge current of 0.15 A, the cell can achieve a discharge time
of 4.38 h and a better fuel utilization of 14.8%, indicating that
a large current discharge is more propitious for the LSGM-based DC-SOFCs
fueled by raw brown coal to achieve higher fuel utilization. This
study exhibits the enormous potential of LSGM as an electrolyte material
for high-performance direct brown coal fuel cells and provides direction
guidance for the optimization of discharge operation of DC-SOFCs directly
utilizing brown coal in consideration of fuel utilization.