Performance of a Composite Inhibitor on Mild Steel in NaCl Solution: Imidazoline, Sodium Molybdate, and Sodium Dodecylbenzenesulfonate

Abstract

Mild steel corrosion is a significant challenge in oil and gas exploitation. Inhibitors are frequently employed to minimize the corrosive impact on mild steel. Mixing corrosion inhibitors is an effective method in reducing the dosage of toxic compounds and expanding the potential applications of inhibitors in NaCl solutions. Herein, a mixed corrosion inhibitor composed of imidazoline (IM), sodium molybdate, and sodium dodecylbenzenesulfonate (SDBS) for mild steel in a 3.5 wt% NaCl solution are investigated by orthogonal experimental design and electrochemical measurement. The imidazoline compound was synthesized and identified using Fourier transform infrared (FTIR) spectroscopy. The inhibitory effect is improved by higher concentrations of sodium molybdate and is further enhanced with the addition of 10 mg/L of SDBS. The electrochemical impedance spectroscopy indicates that the combination of IM (100 mg/L), sodium molybdate (50 mg/L), and SDBS (100 mg/L) results in excellent performance with electrochemical impedance (1.8 kohm·cm2). The mild steel surfaces after electrochemical measurement were analyzed using scanning electron microscopy (SEM). The information can contribute to the development of corrosion inhibitors with high performance or to understand the influence of mixing inhibitors on corrosion processes of mild steels.