This study presents characteristics of tar formed during updraft gasification of biomass by using mass spectrometry and thermogravimetric analysis. Tar content in producer gas is higher at the lower-middle part of the reactor which represents a pyrolytic zone. Tar is composed of C, H, N and O by 70.62%, 10.62%, 0.57% and 18.20%, correspondingly and its HHV is around 35.27 MJkg -1 . ToF-MS analysis for ion mass-to-charge ratio (mz -1 ) indicates high intensities from 280 mz -1 to around 380 mz -1 . In comparison with tar taken from the trap, tar samples captured along the bed heights have relatively low peaks at 500 mz -1 , 555 mz -1 and 615 mz -1 . Devolatilization of tar up to 700 K follows a similar trend regardless of presence or absence of oxidizing agent. Tar has about 22.17% fixed carbon content whose combustion and gasification at heating rate of 20 Kmin -1 occurred above 700 K. Average devolatilization for volatile matter in tar during non-isothermal pyrolysis, combustion and gasification was about 2.29%min -1 . Average degradation of fixed carbon during non-isothermal combustion and non-isothermal gasification was found to be 3.45%min -1 and 0.54%min -1 , respectively. For isothermal combustion and gasification at 1,273 K, degradation of fixed carbon was about 3.73%min -1 and 0.95%min -1 , respectively.