“…Optoelectronic multifunctional materials that own two or more properties in a single entity have emerged as promising next-generation materials for the development of digitization, integration, and miniaturized equipment . Recently, rare-earth ions RE 3+ (e.g., Pr 3+ , Er 3+ , Ho 3+ , La 3+ , Eu 3+ )-modified ferroelectrics, one kind of multifunctional optoelectronic materials possessing both photoluminescence (PL) and ferroelectric properties, have been intensively investigated for the application of power generation, data storage, optical telecommunication, and remote sensing. − Among RE 3+ , Er 3+ is an important activator in upconversion luminescence materials, which are attractive in upconversion lasers, planar waveguide, and bioseparation. , Er-doped ferroelectrics have been verified to be a promising candidate for realizing multifunction; for instance, Er-doped CaBi 4 Ti 4 O 15 and Er-doped (K, Na)NbO 3 ceramics exhibit bright upconversion emission and superior piezoelectric/ferroelectric properties. , …”