IntroductionThere is an increasing demand to find out the biodegradable and environmental friendly fuel to meet the future energy demands. Several legislations were followed for improving the disadvantage of biodiesel fuel such as increased NOx emission and soot particles. To achieve standard emission norms, many studies have been conducted over past few decades. Among them, recent fuel additives namely antioxidants and nanoparticles were preferred for minimizing the NOx emission effectively. Fattah et al., [1] used antioxidants namely monophenolic, 2(3)-tert-Butyl-4-methoxyphenol, 2,6-di-tert-butyl-4-methylphenol, diphenolic, 2-tert-butylbenzene-1,4-diol as additive in calophyllum inophyllum biodiesel blends at 2000 ppm (parts per million) and observed percentage reduction of NOx emission by 3.6 % and improvement in brake specific fuel consumption by 1.5 % along with higher emission of carbon monoxide (CO) and unburned hydrocarbon (HC) in a four cylinder, four stroke, water cooled, indirect injection diesel engine. Varatharajan et al., [2] conducted experimental investigation in computerized four stroke water cooled single cylinder diesel engine by adding antioxidant additives, N,N′-diphenyl-1,4-phenylenediamine and N-phenyl-1,4-phenylenediamine at 1000 and 2000 ppm with soybean biodiesel and observed 14 % increase in CO, 16 % increase in HC emission, 9 % reduction in Nitric oxide (NO) and 0.8 % reduction in brake thermal efficiency (BTE). Similarly, when N, N-diphenyl-1,4-phenylenediamine at 150 ppm was blended with jatropha diesel blends, 16 % reduction in NO was observed with higher emission of HC and CO [3]. From the antioxidant studies, it is observed that antioxidants as additive in fuel was effective for NO reduction, whereas the brake specific consumption, HC and CO emission increases for antioxidant addition. In contrast, when nanoparticles were used as additive in fuel, significant improvement in both performance and emission characteristics were observed.Sajith et al. [4] experimented with cerium oxide nanoparticle at 20, 40 and 60 ppm addition in jatropha biodiesel and observed significant reduction of NOx by 30 % and HC by 40 % in a fourstroke, single cylinder, water-cooled compression ignition. They observed that the significant reduction of NOx and HC emission