2005
DOI: 10.1021/om050479+
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(Perfluoro)alkylsilyl-Substituted 2-[Bis(4-aryl)phosphino]pyridines:  Synthesis and Comparison of Their Palladium Complexes in Methoxycarbonylation of Phenylacetylene in Regular Solvents and Supercritical CO2

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Cited by 35 publications
(22 citation statements)
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“…A molybdenummediated intramolecular double allenic Pauson-Khand reaction was used to prepare dicyclopenta[a,e]pentalenes [1025]. (203) Palladium catalyzed a hydrocarbonylation of phenylethyne using carbon monoxide to form methyl 2-phenylpropenoate with high selectivity [1026]. Rhodium catalyzed a cyclocarbonylation of alkynes forming butenolides using methanal as the CO source (Eq.…”
Section: Carbonylations Of Alkynes (Including the Pauson-khand Reaction)mentioning
confidence: 99%
“…A molybdenummediated intramolecular double allenic Pauson-Khand reaction was used to prepare dicyclopenta[a,e]pentalenes [1025]. (203) Palladium catalyzed a hydrocarbonylation of phenylethyne using carbon monoxide to form methyl 2-phenylpropenoate with high selectivity [1026]. Rhodium catalyzed a cyclocarbonylation of alkynes forming butenolides using methanal as the CO source (Eq.…”
Section: Carbonylations Of Alkynes (Including the Pauson-khand Reaction)mentioning
confidence: 99%
“…High activity (TOF up to 8000 in methanol) and high selectivity (>99%) toward the branched ester product were reported [151]. Imidazolium-based ionic liquids with [PF 6 ] À , [BF 4 ] À , and [GaCl 4 ] À counterions were synthesized and used in hydroethoxycarbonylation of styrene.…”
Section: Hydroalkoxycarbonylationmentioning
confidence: 99%
“…Deelman, Elsevier and Van Koten et al recently reported on the methoxycarbonylation of phenylacetylene [38] by 1H,1H,2H,2H-perfluoroalkylsilyl-substitut- So far no studies that address the recycling of alkoxycarbonylation catalysts from supercritical CO 2 solutions have been reported. However, this may well become feasible in the near future by, e.g., nanofiltration [7e,39] or selective precipitation of the catalyst by variation of the pressure.…”
Section: Use Of Supercritical Co 2 In Alkoxycarbonylation Reactionsmentioning
confidence: 99%
“…Furthermore, one can find terms describing specific types of reactions, such as hydroxycarbonylation (formation of carboxylic esters), Figure 13. Functionalized 2-[bisA C H T U N G T R E N N U N G (4-aryl)phosphino]pyridine ligands used by Deelman, Elsevier, van Koten et al [38] …”
Section: Referencesmentioning
confidence: 99%