Perfluorinated porphyrazines

Perfluorinated Porphyrazines. 5. Perfluoro-a,b-dicyanostylbene: Molecular Structure and Derived (Sub)Porphyrazine Complexes with IIIa Group Elements

“…[(X)MPAH 40 ] (M = Al III , Ga III and In III ), [18] can be easily obtained directly from trans-dicyanostylbene (i.e. fumaric acid derivative) by melting with corresponding metal halides.…”

“…Spectra of corresponding non-fluorinated complexes adopted from ref. [18,27] are shown by dotted lines. 200 cm -1 ) < In III (28 nm, 680 cm -1 ).…”

“…Thus, S N Ar reaction was employed for preparation of butoxy and water soluble galactosyl derivatives from [ZnPAF 40 ], in which up to eight F-atoms in p-positions of phenyl rings can be substituted. [7] It was also demonstrated by Nemykin and coauthors [8] that m-oxodiiron(III) complex, [m-O(FePAF 40 ) 2 ], is an effective catalyst of oxidation reactions.…”