Abstract:Surprisingly little is known about fluorinated tin(II) alkoxides. Here the synthesis and characterization of Sn(OR F ) 2 [OR F = OC(CF 3 ) 3 ] and the crystal structures of its adducts with phenanthroline and dppe are reported. In addition, its ate complex [Sn(OR F ) 3 ]was
Planar-chiral homologues of the important synthon 1,1′-diaminoferrocene, which bear a single additional substituent adjacent to an amino group, are efficiently synthesised on a gram scale.
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