A quaternionic Hadamard matrix (QHM) of order n is an $$n\times n$$
n
×
n
matrix H with non-zero entries in the quaternions such that $$HH^*=nI_n$$
H
H
∗
=
n
I
n
, where $$I_n$$
I
n
and $$H^*$$
H
∗
denote the identity matrix and the conjugate-transpose of H, respectively. A QHM is dephased if all the entries in its first row and first column are 1, and it is non-commutative if its entries generate a non-commutative group. The aim of our work is to provide new constructions of infinitely many (non-commutative dephased) QHMs; such matrices are used by Farkas et al. (IEEE Trans Inform Theory 69(6):3814–3824, 2023) to produce mutually unbiased measurements.