Pentafluoro-λ6-sulfanyl (SF5) perfluoroalkyl iodides-synthesis and reaction with ethylene and tetrafluoroethylene

Halogen displacement chemistry with silver and alkali metal salts: Preparation of SF5-esters, alcohols, aliphatic olefins, acids and an iodide

“…The compounds SF 5 (CH 2 ) 3 Br [15], SF 5 (CF 2 ) 4 (CH 2 ) 2 I [17] and SF 5 CHBrCH 2 Br [3] were prepared according to the literature method. SF 5 CH 2 CH 2 Br was first prepared by Merrill [18].…”

Preparation and Utility of Organic Pentafluorosulfanyl-Containing Compounds

“…Replacement of I 2 with (ICF 2 ) 2 was also found to produce SF 5 (CF 2 ) 2 I. Further exploration of the chemistry of SF 5 (CF 2 ) 2 I revealed that adducts with unsaturated organic compounds occur under conditions comparable to those used for SF 5 X additions …”