The article presents the peculiarities of the mineral formation in the "lime-mineral modifier from amorphized raw material" system depending on the composition of an additive. It is shown that the chemical activity of modifying components in terms of CaO binding and the formation of crystalline neoplasms are significantly different. The similarity of the crystalline ligament of autoclave systems has been established regardless of the raw material composition of a modifier, which is conditioned by the specificity of the mineral components of raw materials and their ability to interact. At the same time for the formation of the maximum amount of the newly formed substance of the hydrosilicate composition, a different amount of the additive is necessary, which is connected with its initial activity.