“…Analytical tools such as X‐ray fluorescence, scanning electron microscopy, and energy dispersive X‐ray spectroscopy are routinely used for elemental analysis of paints, while Raman and infrared spectroscopies have successfully been evaluated as powerful tools for the identification and discrimination of chemical composition, especially when paired with multivariate analysis methods such as principal component analysis (PCA). In addition, internationally adopted databases such as the Paint Data Query contain infrared spectral data from over 21 000 paint samples to assist in chemical identification for further discrimination . Techniques currently available and examined for such applications include UV–visible/fluorescence imaging, near infrared imaging, and Raman mapping and imaging, with a roughly 5 μm image resolution to resolve small features, such as recovered paint evidence in the form of smears, droplets, embedded chips, and partial layers (one or two top layers only).…”