Pd NPs Decorated on POPs as Recyclable Catalysts for the Synthesis of 2‐Oxazolidinones from Propargylic Amines via Atmospheric Cyclizative CO<sub>2</sub> Incorporation

Ghosh, S.; Riyajuddin, Sk; Sarkar, Somnath; Ghosh, Kaushik

doi:10.1002/cnma.201900505

Cited by 32 publications

(16 citation statements)

References 93 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Islam and co-workers reported the synthesis of two different knitting polymers, following method-1, containing benzene and benzylamine or para-methoxybenzylamine. 101 Subsequently, Pd NPs were dispersed over the network by coordination of PdCl 2 and reduction with ethylene glycol at 150 °C, resulting in the materials named Pd@BBA-1 and Pd@ BBA-2, respectively (Figure 15f). N 2 adsorption/desorption isotherms confirmed that Pd NPs did not dramatically decrease the specific surface area of the resulting materials.…”

Section: Nanoparticles Supported On Knitting Arylmentioning

confidence: 99%

Metal Catalysis with Knitting Aryl Polymers: Design, Catalytic Applications, and Future Trends

Valverde‐González

Iglesias

2021

Chem. Mater.

View full text Add to dashboard Cite

In 2011, a new type of hyper-cross-linked polymers (HCPs) arose, known as knitting aromatic polymers (KAPs), characterized by their extraordinary chemical and thermal stability, by their porosity properties, and above all, for the simplicity of their synthesis based on the union of aromatic monomers, without any previous functionalization. The next logical step was the incorporation of metals within these networks, as support for different soluble molecular catalysts or metal nanoparticles (NPs). Thus, the number of metal-containing KAPs has been gradually growing in the past decade, and we have considered that now, in the 10th anniversary of the first KAPs reported, a review of all the metal-containing KAPs and their application as heterogeneous metal catalysts is mandatory. In this review, the most relevant characteristics of all KAPs that contain metals are summarized, divided into two large groups, either as metal complexes or as metal NPs, and classified according to the type of metal incorporated. Finally, the catalytic activities were compared based on the metal employed in each studied reaction, and the future goals of these types of materials are commented on.

show abstract

Section: Nanoparticles Supported On Knitting Arylmentioning

confidence: 99%

Metal Catalysis with Knitting Aryl Polymers: Design, Catalytic Applications, and Future Trends

Valverde‐González

Iglesias

2021

Chem. Mater.

View full text Add to dashboard Cite

show abstract

“…heterogenisation [290][291][292][293][294] of organocatalysts and organometallic complexes were explored as well as the possibilities of MOFs as catalysts. 295,296 Nevertheless, the use of ordered micro and mesoporous materials has been almost unexplored.…”

Section: Synthesis Of Carbamatesmentioning

confidence: 99%

Advanced zeolite and ordered mesoporous silica-based catalysts for the conversion of CO₂to chemicals and fuels

2023

View full text Add to dashboard Cite

show abstract

“…Another important type of CO 2 fixation reaction is the production of oxazolidinones through carboxylative cyclization. 25 Oxazolidinones are a versatile class of N-containing heterocyclic compound having immense applications as chiral auxiliaries in asymmetric synthesis of biologically active compounds. 26 The said compound is found in many commercially available drugs (like beflooxatone, cimoxatone, zolmitriptan, toloxatone, etc.)…”

Section: Introductionmentioning

confidence: 99%

Zn(II)-Embedded Nanoporous Covalent Organic Frameworks for Catalytic Conversion of CO₂ under Solvent-Free Conditions

Haque

Biswas

Ghosh

et al. 2021

ACS Appl. Nano Mater.

Self Cite

View full text Add to dashboard Cite

Covalent organic frameworks (COFs) have been gaining substantial attention over the past decade due to their developing crystalline porous polymeric nature linked by strong covalent bonds and widespread applications in various fields. Currently, three-dimensional COFs (3D COFs) are engaging the spotlight due to their distinctive porous features, greater surface area, and exceptional performances in comparison with formerly published two-dimensional (2D) frameworks with the AA-stacking layered mode. In this paper, we present, for the first time, a nanoporous 3D-COF-based zinc(II) catalyst (Zn@RIO-1), which shows an efficient pathway for the chemical conversion of carbon dioxide to produce α-alkylidene cyclic carbonates and oxazolidinones from propargylic alcohols. The microporous material with a high surface area (312.61 m2/g) facilitates both types of catalytic reactions under atmospheric CO2 pressure. More importantly, easily recyclable and reusable catalysts produced moderate to high yields of desired carbonates as well as oxazolidinone products under solvent-free conditions. This study emphasizes the capability of nanoporous 3D-COF-based material in the catalysis field, more specifically in the field of CO2 capture and chemical fixation to fine chemicals. These results pave a spectacular pathway for the chemical fixation of CO2 into α-alkylidene cyclic carbonates and oxazolidinones from propargylic alcohols using 3D-COF as a potential heterogeneous ligand under sustainable conditions (i.e., solvent-free).

show abstract

Pd NPs Decorated on POPs as Recyclable Catalysts for the Synthesis of 2‐Oxazolidinones from Propargylic Amines via Atmospheric Cyclizative CO₂ Incorporation

Abstract: A novel approach has been taken for the synthesis of a microporous polymeric materials of BBA-1 and BBA-2

Cited by 32 publications

References 93 publications

Metal Catalysis with Knitting Aryl Polymers: Design, Catalytic Applications, and Future Trends

Metal Catalysis with Knitting Aryl Polymers: Design, Catalytic Applications, and Future Trends

Advanced zeolite and ordered mesoporous silica-based catalysts for the conversion of CO₂to chemicals and fuels

Zn(II)-Embedded Nanoporous Covalent Organic Frameworks for Catalytic Conversion of CO₂ under Solvent-Free Conditions

Contact Info

Product

Resources

About

Pd NPs Decorated on POPs as Recyclable Catalysts for the Synthesis of 2‐Oxazolidinones from Propargylic Amines via Atmospheric Cyclizative CO2 Incorporation

Abstract: A novel approach has been taken for the synthesis of a microporous polymeric materials of BBA-1 and BBA-2

Cited by 32 publications

References 93 publications

Metal Catalysis with Knitting Aryl Polymers: Design, Catalytic Applications, and Future Trends

Metal Catalysis with Knitting Aryl Polymers: Design, Catalytic Applications, and Future Trends

Advanced zeolite and ordered mesoporous silica-based catalysts for the conversion of CO2to chemicals and fuels

Zn(II)-Embedded Nanoporous Covalent Organic Frameworks for Catalytic Conversion of CO2 under Solvent-Free Conditions

Contact Info

Product

Resources

About

Pd NPs Decorated on POPs as Recyclable Catalysts for the Synthesis of 2‐Oxazolidinones from Propargylic Amines via Atmospheric Cyclizative CO₂ Incorporation

Advanced zeolite and ordered mesoporous silica-based catalysts for the conversion of CO₂to chemicals and fuels

Zn(II)-Embedded Nanoporous Covalent Organic Frameworks for Catalytic Conversion of CO₂ under Solvent-Free Conditions