2007
DOI: 10.1007/s10562-007-9047-3
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Pd(111) versus Pd–Au(111) in carbon monoxide oxidation under elevated pressures

Abstract: The oxidation of CO on Pd(111) and Pd 70 Au 30 (111) has been studied under pressures upto 100 Torr. Gold is found to decrease the surface activity by inhibiting oxygen dissociation. For a sufficient conversion time depending on the CO coverage and the surface identity, a dramatic boost of activity occurs. This is ascribed to a switch from CO-induced inhibition of O 2 adsorption to a regime determined by CO adsorption. The other kinetic features are explained by oxidation of palladium and adsorption-induced re… Show more

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Cited by 28 publications
(35 citation statements)
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“…[30][31][32][33][34][35][36][37][38][39][40] In the case of Pd(100), it has been shown experimentally that the higher activity of this surface towards CO oxidation at these conditions coincides with the presence of the √ 5 surface oxide. 30,32,35,38,39,41 Kinetic Monte-Carlo simulations support the view that a surface oxide on Pd(100) could be responsible for increased reactivity.…”
mentioning
confidence: 96%
“…[30][31][32][33][34][35][36][37][38][39][40] In the case of Pd(100), it has been shown experimentally that the higher activity of this surface towards CO oxidation at these conditions coincides with the presence of the √ 5 surface oxide. 30,32,35,38,39,41 Kinetic Monte-Carlo simulations support the view that a surface oxide on Pd(100) could be responsible for increased reactivity.…”
mentioning
confidence: 96%
“…However, some studies also indicate Pd surfaces covered 37 by atomic oxygen as highly active [8,17], and generally both will exhibit activity. For Pd(100), the 38 presence of a (√5x√5)R27° surface oxide (henceforth denoted √5) is found to exist when the surface 39 is highly active towards CO oxidation [5,6,8,10,14,17,18], and this is consistent with the reaction 40 following a Mars-van Krevelen mechanism with gas-phase CO reacting with the surface oxide to 41 form CO2 [5][6][7]9,11,[13][14][15]19]. The presence of the surface oxide during high CO2 production is also 42 supported by kinetic Monte-Carlo simulations [20,21].…”
Section: Introductionmentioning
confidence: 66%
“…Surface oxides rather than surfaces covered by chemisorbed oxygen have been 35 observed as the most active towards CO oxidation under near ambient as well as more realistic 36 conditions (above ambient pressure) [5][6][7][8][9][10][11][12][13][14][15][16]. However, some studies also indicate Pd surfaces covered 37 by atomic oxygen as highly active [8,17], and generally both will exhibit activity.…”
Section: Introductionmentioning
confidence: 99%
“…Metal/metal interfaces show novel physical and chemical properties [4,9,[14][15][16]. In particular, bimetallic surfaces involving gold [7,[17][18][19] are extensively investigated due to the high catalytic activity of nanostructured gold systems [20][21][22][23].…”
Section: Introductionmentioning
confidence: 99%