Pb-Sb-S ternary system

Bakhtiyarly, I. B.; Аждарова, Д. С.; Mamedov, S. G.

doi:10.1134/s0036023613060041

Russ. J. Inorg. Chem.

2013

DOI: 10.1134/s0036023613060041

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Pb-Sb-S ternary system

I. B. Bakhtiyarly

Д. С. Аждарова

S. G. Mamedov

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2016

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“…The compound PbSnS 2 crystallizes in the rhombic system [5,6]. EXPERIMENTAL Alloys for investigation were obtained from binary sulfides PbS, Bi 2 S 3 , and SnS in evacuated quartz ampoules at a temperature of 950-1000 K. The composition of four-component samples was calculated from the weights of sulfides PbS, SnS and Bi 2 S 3 , the contents of which in samples during their heat treatment remained unchanged.…”

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Phase equilibria in the PbBi2S4–PbSnS2 system

Гурбанов

Mamedov

2016

Russ. J. Inorg. Chem.

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The PbBi 2 S 4 -PbSnS 2 system was studied by physicochemical analysis methods, and its state diagram was constructed. The system is partially quasi-binary; regions of solid solutions based on PbSnS 2 are determined. At a ratio between the initial components of 1 : 1, congruently melting compound Pb 2 SnBi 2 S 6 forms. The unit cells parameters of Pb 2 SnBi 2 S 6 crystallizing in the orthorhombic system are: a = 15.60 Å, b = 7.80 Å, c = 4.26 Å; space group Pbmm.Bismuth, tin, and lead sulfides are promising semiconductors with photosensitive properties [1,2]. However, the narrow operating temperature range, low melting points, and low mechanical strength limit their practical use. Therefore, study of interactions and phase equilibria in the section PbBi 2 S 4 -PbSnS 2 in the quasi-ternary system SnS-Bi 2 S 3 -PbS is of not only scientific but also practical interest.The compound PbBi 2 S 4 melts incongruently at 980 K [3,4].

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Phase equilibria in the PbBi2S4–PbSnS2 system

Гурбанов

Mamedov

2016

Russ. J. Inorg. Chem.

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Pb-Sb-S ternary system

Cited by 1 publication

References 2 publications

Phase equilibria in the PbBi2S4–PbSnS2 system

Phase equilibria in the PbBi2S4–PbSnS2 system

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