Patternsin the synthesis processes, the microstructure and properties of strontium-anorthite ceramics modified by glass of spodumene composition

Zaichuk, Oleksandr; Amelina, Аleksandra; Hordieiev, Yurii; Kalishenko, Yuliia; Sribniak, Nataliia; Halushka, Serhii; Borodai, Dmytro; Borodai, Artem

doi:10.15587/1729-4061.2020.216754

Cited by 8 publications

(1 citation statement)

References 24 publications

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“…Cordierite glass ceramics surpasses strontium-anorthite and celsian ceramics, primarily in heat resistance and strength indicators [13][14][15]. In addition, cordierite is characterized by low specific weight.…”

Section: Introductionmentioning

confidence: 99%

Determining patterns in the formation of cordierite phase during the synthesis of density-sintered low-temperature ceramics based on glasses of the MgO–Al2O3–SiO2 system

Zaichuk

Amelina

Kalishenko

et al. 2022

EEJET

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The search for effective modifiers of the structure of densely baked cordierite ceramics to reduce the firing temperature is a relevant task but typically requires a large amount of experimental research. The object of this study is the reaction of the formation of the cordierite phase with the participation of glass components of the eutectic compositions of the MgO– Al2O3–SiO2 system under low-temperature firing conditions. In this case, thermodynamic analysis was used as a tool to assess the probability of chemical reactions. Thermodynamic analysis can significantly reduce the volume of the experimental sample. This paper reports the results of theoretical and experimental studies into the features of the course of chemical reactions with the participation of glass components of eutectic compositions of the MgO–Al2O3–SiO2 system. It was revealed that once the stoichiometric ratio is maintained, the resulting product of the interaction between the components of eutectic glasses of the MgO–Al2O3–SiO2 system with charging components is cordierite. Changes in the mineralogical composition of cordierite compositions depending on the firing temperature have been determined. The formation of the cordierite phase is preceded by the process of transformation of meta kaolinite Al2O3·2SiO2, which is a product of kaolin dehydration, into mullite 3Al2O3·2SiO2. Subsequently, the formation of cordierite (in addition to crystallizing directly from eutectic glasses) occurs with the participation of the mullite phase. The formation of the cordierite phase occurs in several stages and is completed at a temperature of 1300 °C. The established features of the reactions of cordierite formation make it possible to determine the most optimal compositions for glasses of the MgO–Al2O3–SiO2 system to obtain low-temperature cordierite ceramics with a high degree of sintering. At the same time, it is also possible to control the phase composition of ceramics and its properties

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Section: Introductionmentioning

confidence: 99%

Determining patterns in the formation of cordierite phase during the synthesis of density-sintered low-temperature ceramics based on glasses of the MgO–Al2O3–SiO2 system

Zaichuk

Amelina

Kalishenko

et al. 2022

EEJET

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Aspects of development and properties of densely sintered of ultra-high-frequency radio-transparent ceramics of cordierite composition

Zaichuk

Amelina

Kalishenko

et al. 2021

J. Korean Ceram. Soc.

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Glass formation and properties of glasses in the system SrO–B2O3–SiO2–xAl2O3 (x=0; 10 mol.%)

Hordieiev¹,

Amelina²

2021

Vopr. Khim. Khim. Tekhnol.

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The paper shows the prospects of the system SrO–Al2O3–B2O3–SiO2 as a basis for the synthesis of new vitreous and glass-ceramic materials, which are widely used as electrical insulated and high-temperature coatings, for sealing of solid oxide fuel cells, and in the production of heat resistant materials. We experimentally established the conditions of glass formation, regions of glass-forming melts and properties of glasses, the chemical composition of which is limited by the following content of components (mol.%): SrO 30–80, B2O3 10–60, SiO2 10–60, and Al2O3 0–10. It is shown that during the synthesis of glasses in the corundum crucible at the temperature of 13500С the region of glass formation in the system SrO–B2O3–SiO2 is limited by the following content of components (mol.%): SrO 30–60, B2O3 10–60, and SiO2 10–50. It is found that the introduction of Al2O3 to the composition of these glasses expands the region of glass formation towards increase of the SiO2 content in the glass up to 60 mol.%. Experimentally determined values of glass properties are within the following limits: coefficient of linear thermal expansion (67–118)10–7 К–1; glass transition temperature 570–6600С; dilatometric softening point 580–7000С; and density 2.62–3.71 g cm–3. The established patterns of influence of the components and conditions of glass formation on the physical and chemical characteristics of glasses may serve as an experimental basis for designing of new materials with a complex of specified properties, which allows solving the problems of their practical use.

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Patternsin the synthesis processes, the microstructure and properties of strontium-anorthite ceramics modified by glass of spodumene composition

Cited by 8 publications

References 24 publications

Determining patterns in the formation of cordierite phase during the synthesis of density-sintered low-temperature ceramics based on glasses of the MgO–Al2O3–SiO2 system

Determining patterns in the formation of cordierite phase during the synthesis of density-sintered low-temperature ceramics based on glasses of the MgO–Al2O3–SiO2 system

Aspects of development and properties of densely sintered of ultra-high-frequency radio-transparent ceramics of cordierite composition

Glass formation and properties of glasses in the system SrO–B2O3–SiO2–xAl2O3 (x=0; 10 mol.%)

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