Patterning of Polymers on a Substrate via Ink‐Jet Printing of a Coordination Polymerization Catalyst

Huber, J. Robert; Amgoune, Abderrahmane; Mecking, Stefan

doi:10.1002/adma.200702702

Cited by 10 publications

(5 citation statements)

References 37 publications

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“…An early example was the synthesis of a library of minerals as thin films on a single 'chip' using a sequential masking and unmasking procedure with ion sputtering to produce a range of material compositions [7]. Subsequently, many variations on this theme of combining components to create a range of material types and/or compositions have been published including photoluminescent composite materials [8], polymer films [9], conductive polymers for the creation of electronic circuitry components [10,11], metal salt catalysts [12], transition metal catalysts [13], metal nanoparticles [14,15], ceramics [16][17][18] and organic light emitting diodes [19].…”

Section: Introductionmentioning

confidence: 99%

High throughput methods applied in biomaterial development and discovery

et al. 2010

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The high throughput discovery of new materials can be achieved by rapidly screening many different materials synthesised by a combinatorial approach to identify the optimal material that fulfils a particular biomedical application. Here we review the literature in this area and conclude that for polymers, this process is best achieved in a microarray format, which enable thousands of cell-material interactions to be monitored on a single chip. Polymer microarrays can be formed by printing pre-synthesised polymers or by printing monomers onto the chip where on-slide polymerisation is initiated.The surface properties of the material can be analysed and correlated to the biological performance using high throughput surface analysis, including time-of-flight secondary ion mass spectrometry (ToF-SIMS), Xray photoelectron spectroscopy (XPS) and water contact angle (WCA) measurements. This approach enables the surface properties responsible for the success of a material to be understood, which in turn provides the foundations of future material design. The high throughput discovery of materials using polymer microarrays has been explored for many cell-based applications including the isolation of specific 2 cells from heterogeneous populations, the attachment and differentiation of stem cells and the controlled transfection of cells.Further development of polymerisation techniques and high throughput biological assays amenable to the polymer microarray format will broaden the combinatorial space and biological phenomenon that polymer microarrays can explore, and increase their efficacy. This will, in turn, result in the discovery of optimised polymeric materials for many biomaterial applications.

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Section: Introductionmentioning

confidence: 99%

High throughput methods applied in biomaterial development and discovery

et al. 2010

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“…The conductive circuit of PA could be generated on a flexible substrate via the inkjet printing of a coordination polymerization catalyst. 93 Sensors could also be fabricated by inkjet printing PTi onto the array of transduction electrodes, which could demonstrate the sensitivity and selectivity of detection and discrimination of volatile organic compounds with the electrochemical property of PTi. 94 In addition, the organic conductive material could be used in optoelectronic devices with a good light transmittance, 95,96 while the conductivity of the organic conductive material is still far below that of the metal.…”

Section: Printable Organic Conductive Materialsmentioning

confidence: 99%

Fabricating flexible conductive structures by printing techniques and printable conductive materials

Sun

Jia

et al. 2022

J. Mater. Chem. C

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“…3,4 In this scenario, the poor solubility of rigid PAE CPs is overcome by the introduction of alkyl chains in the CPs. With the improved solubility behaviour of PAE CPs, they are mostly used in printing 5,6 and device fabrication for natural energy conversion. 7 These notable properties of PAE CPs have attracted many researchers to take up active research in the development of D-A PAE CPs using the palladium cross-coupling reaction of the Sonogashira coupling method.…”

Section: Introductionmentioning

confidence: 99%

Acetophenone and thiophene side‐arm polyaryleneethynylene conjugated polymers for enrichment of electronic applications

Kumar

Chandramohan²,

Priya

et al. 2020

Polymer International

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In the present work, a new type of semiconducting acetophenone and thiophene side‐arm based polyaryleneethynylene (PAE) conjugated polymers (CPs) were synthesized using the Heck–Sonogashira cross‐coupling reaction. The new type of monomers and APAEC8, APAEC12, APAEF8, TPAEC8, TPAEC12, and TPAEF8 (PAE CPs) were synthesized and characterized using Fourier transform IR, NMR and high resolution mass spectrometry studies. The average molecular weight of the CPs was determined using gel permeation chromatography. The data obtained from optical properties in the UV–visible and photoluminescence spectral studies were used to calculate the values of the Stokes shift. Among the six CPs studied, TPAEC8 was found to possess a lower optical band gap (Eg = 2.112 eV) than those of the other CPs. The data obtained from different studies, it was found that TPAEC8 exhibits better properties than the other CPs and can be used in the field of organic based photonic, electronic and other sensor applications. © 2020 Society of Chemical Industry

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Patterning of Polymers on a Substrate via Ink‐Jet Printing of a Coordination Polymerization Catalyst

Cited by 10 publications

References 37 publications

High throughput methods applied in biomaterial development and discovery

High throughput methods applied in biomaterial development and discovery

Fabricating flexible conductive structures by printing techniques and printable conductive materials

Acetophenone and thiophene side‐arm polyaryleneethynylene conjugated polymers for enrichment of electronic applications

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