Pathway to fully-renewable biobased polyesters derived from HMF and phenols

Tavana, Jalal; Faysal, Atik; Vithanage, Anushka; Gramlich, William M.; Schwartz, Thomas J.

doi:10.1039/d1py01441b

Cited by 1 publication

(1 citation statement)

References 84 publications

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“…Gramlich and Schwartz developed a synthesis method for functionalized δ-lactones from biobased hydroxymethylfurfural. 75 While simple alkyl δ-lactones exhibited good efficiency, the presence of additional chemical units influenced TBD activity (Scheme 17). A sidechain with a methoxy end inhibited TBD, while a phenoxy chain end underwent polymerization.…”

Section: -Membered Ring Lactones: Lactides and δ-Valerolactonesmentioning

confidence: 99%

Triazabicyclodecene: A versatile catalyst for polymer synthesis

Kim,

Lee,

Lee

2023

Journal of Polymer Science

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This comprehensive review aims to provide an in‐depth analysis of the catalytic performance of 1,5,7‐triazabicyclo[4,4,0]dec‐5‐ene (TBD) in polymer synthesis. TBD, a well‐established organic superbase, possesses a distinctive bifunctional character that grants it exceptional capabilities, particularly in processes such as transesterification or transamidation. TBD has garnered considerable attention since its initial report by Hedrick and Waymouth in 2006, and it has played a pivotal role in diverse polymerization reactions. Its versatility spans various polymerization modes, including chain‐growth and step‐growth polymerization, post‐polymerization modification, and network thermoset formation. More recently, its utility has extended to the green chemical recycling of polymers. By providing an encompassing overview of TBD's historical journey, this review delves into its past accomplishments while shedding light on its present and future potential to organocatalysts in polymer science.

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Section: -Membered Ring Lactones: Lactides and δ-Valerolactonesmentioning

confidence: 99%