Passive Permeate-Side-Heated Solar Thermal Membrane Distillation: Extracting Potable Water from Seawater, Surface Water, and Municipal Wastewater at High Single-Stage Solar Efficiencies

Abstract

Globally, hundreds of millions of people still drink untreated surface water due to the lack of even a basic drinking water service and urgently need economical off-grid water treatment devices. A passive, single-stage, permeate-side-heated solar thermal membrane distillation system is developed for extracting potable water from seawater, surface water, and municipal wastewater. The carbon blackcoated permeate side of a 0.45 μm PVDF membrane absorbs solar radiation and evaporates the feedwater within the pores of the membrane. Under natural sunlight, the distillate flux was 8.56 kg/(m 2 •day) at an average daytime irradiance of 652 W/m 2 , equivalent to the system energy efficiency of 67.5%, the highest so far for single-stage solar distillation under natural sunlight. This system removed all the heterotrophic bacteria, 99.9% turbidity, and 99.6% chemical oxygen demand (COD) from wastewater and reduced electrical conductivity by 99.9% from seawater, during the first 8 h of operation under simulated sunlight (1800 W/m 2 ). The operation continued for 32, 18, and 10 days on average for seawater, canal water, and wastewater, respectively, until the feedwater penetrated the membrane. Throughout longterm experiments, the distillate had a decreasing flux within 0.98−1.55 kg/(m 2 •h), a steady pH of 7.2−7.9, a steady turbidity of 0.09−0.21 NTU, a steady electrical conductivity within 0.003−0.451 mS/cm, and an increasing COD within 1.9−9.2 mg/L regardless of the type of feedwater. Comprehensive water quality tests show that the distillate extracted from all types of feedwater meets U.S. drinking water standards for total coliform, 22 heavy metals and minerals, 7 anions, 5 physical factors, and 50 volatile organic compounds and will be safe to drink in real-world applications.

Carbon Emission Calculations and Reductions in Membrane Water Treatment: A Review

“…Exploring the balance between high quality effluent and low carbon emissions is a future concern for water treatment technologies, especially membrane technologies. First, the use of natural materials such as nanocellulose (NC) and renewable energy sources to drive membrane technologies has demonstrated excellent performance and very low energy consumption. − Second, emerging anaerobic membrane bioreactors (AnMBRs) enhance pollutant removal, bioenergy production, and resource recycling by integrating the benefits of anaerobic digestion and membrane technologies, which should enable carbon footprint neutral anaerobic wastewater treatment plants. ,, Finally, resource recovery provides an effective pathway for carbon reduction, avoiding both resource waste and carbon offsetting. However, there are still few studies on the emission reduction of resource utilization in wastewater, and the lack of long-term consideration of membrane module recycling still requires in-depth research.…”