Passive Direct Methanol–Hydrogen Peroxide Fuel Cell with Reduced Graphene Oxide–Supported Prussian Blue as Catalyst

Lu, Biaowu; Yuan, Wei; Su, Xiaoqing; Zhuang, Zhiqiang; Ke, Yuzhi; Tang, Yong

doi:10.1002/ente.201901360

Cited by 11 publications

(4 citation statements)

References 53 publications

(60 reference statements)

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“…[241] The advances in catalyst technology have led to more efficient and durable FCs that can operate at higher temperatures, reducing the need for expensive cooling systems. [242] Additionally, catalysts are vital components in FCs, as they facilitate the electrochemical reactions. [243] Currently, most FC catalysts use platinum or other precious metals, which are costly and limited in supply.…”

Section: Future Outlook Of Fuel Cellsmentioning

confidence: 99%

“…In case of FC, the catalyst's role is to accelerate the reactions which occur when hydrogen and oxygen are combined to produce electricity [241] . The advances in catalyst technology have led to more efficient and durable FCs that can operate at higher temperatures, reducing the need for expensive cooling systems [242] . Additionally, catalysts are vital components in FCs, as they facilitate the electrochemical reactions [243] .…”

Section: Future Outlook Of Fuel Cellsmentioning

confidence: 99%

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A Critical Review on Hydrogen Based Fuel Cell Technology and Applications

Gupta,

Toksha,

Rahaman

2023

The Chemical Record

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The research in energy storage and conversion is playing a critical role in energy policy as the innovation and technological progress are essential for achieving the energy transition and climate neutrality goals. Hydrogen Fuel Cell technology is considered a strategic element in the pursuit of sustainable and clean energy solutions. This technology is increasingly gaining attention in recent years as a potential substitute to conventional non‐renewable energy sources. Fuel cell technology can be employed for domestic/commercial use along with powering the transportation sector which currently employs the use of conventional battery systems. However, these systems pose severe limitations with respect to longer charging times and limited distance range. This review article aims at providing a comprehensive methodical overview of hydrogen‐based fuel cell technology along with key concepts, present day scenarios, including overview of the market and industry trends, government policies and initiatives, along with major stakeholders involved in scaling up the technology for mass consumption. The outlook of fuel cells, including their capability to revolutionise the energy sector is discussed. The technological advancements and breakthroughs on the horizon along with the challenges and safety concerns related to the widespread acceptance of fuel cells are analysed.

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Section: Future Outlook Of Fuel Cellsmentioning

confidence: 99%

Section: Future Outlook Of Fuel Cellsmentioning

confidence: 99%

A Critical Review on Hydrogen Based Fuel Cell Technology and Applications

Gupta,

Toksha,

Rahaman

2023

The Chemical Record

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“…Nevertheless, according to the authors, in general, the PDs obtained in this study were higher than those described in the literature. Another less disruptive approach can be found in the work reported by Lu et al [177], which studied a passive DMFC using H 2 O 2 as the oxidant, i.e., a passive direct methanol-hydrogen peroxide fuel cell (DMHPFC). This fuel cell had a theoretical voltage of 1.76 V (higher than 1.21 V for the traditional DMFC) and could be used in an oxygen-free environment.…”

Section: Alternative Oxidantsmentioning

confidence: 99%

Passive Small Direct Alcohol Fuel Cells for Low-Power Portable Applications: Assessment Based on Innovative Increments since 2018

2022

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Passive small direct alcohol fuel cells (PS-DAFCs) are compact, standalone devices capable of electrochemically converting the chemical energy in the fuel/alcohol into electricity, with low pollutant emissions and high energy density. Thus, PS-DAFCs are extremely attractive as sustainable/green off-grid low-power sources (milliwatts to watts), considered as alternatives to batteries for small/portable electric and electronic devices. PS-DAFCs benefit from long life operation and low cost, assuring an efficient and stable supply of inherent non-polluting electricity. This review aims to assess innovations on PS-DAFC technology, as well as discuss the challenges and R&D needs covered on practical examples reported in the scientific literature, since 2018. Hence, this compilation intends to be a guidance tool to researchers, in order to help PS-DAFCs overcome the barriers to a broad market introduction and consequently become prime renewable energy converters and autonomous micropower generators. Only by translating research discoveries into the scale-up and commercialization process of the technology can the best balance between the economic and technical issues such as efficiency, reliability, and durability be achieved. In turn, this will certainly play a crucial role in determining how PS-DAFCs can meet pressing sustainable energy needs.

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“…[9,10] The structural parameters include the physical parameters of the membrane electrode assembly (MEA) and the geometric parameters of the flow field structure. [11][12][13] Studies showed that optimizing the operating parameters and the cell structure are two effective ways to enhance DMFC performance. [14][15][16][17] Yang et al [18] developed a serpent flow fields structure for DMFC, and the results showed that with this structure, the DMFCs delivered better performance under various conditions.…”

mentioning

confidence: 99%

Adaptive Joint Multiobjective Operating Parameters’ Optimization for Active Direct Methanol Fuel Cells

Zhang,

Liu,

Zhao

2024

Energy Tech

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The operating parameters of the active direct methanol fuel cell (DMFC) are essential factors affecting its power delivery performance. Different operating parameters lead to variations in the amount of methanol crossover in a DMFC, which might cause overpotential and cathode catalyst poisoning. Due to the complexity of the DMFC system, changes in operating conditions, and correlations among these parameters, it is challenging to maintain output power density while reducing the negative effects of methanol crossover. This paper proposes an adaptive joint optimization method for fuel cell operating parameters. The principle operating parameters are selected by the orthogonal tests, which include an adaptive numerical simulation and multiobjective optimization regarding cell output power density and methanol crossover. The selected parameter combinations are verified by an evaluation model that quantifies the influences of operating parameters on the active DMFC power density and its methanol crossover, where the nonlinear mapping function for the two optimization objectives is obtained. The nondominated sorting genetic algorithm‐II (NSGA‐II) is applied to rapidly obtain the optimal combination. The results show that with the optimal parameters, the maximum power density is increased by 16.7% and the methanol crossover is reduced by 35.1%.

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Passive Direct Methanol–Hydrogen Peroxide Fuel Cell with Reduced Graphene Oxide–Supported Prussian Blue as Catalyst

Cited by 11 publications

References 53 publications

A Critical Review on Hydrogen Based Fuel Cell Technology and Applications

A Critical Review on Hydrogen Based Fuel Cell Technology and Applications

Passive Small Direct Alcohol Fuel Cells for Low-Power Portable Applications: Assessment Based on Innovative Increments since 2018

Adaptive Joint Multiobjective Operating Parameters’ Optimization for Active Direct Methanol Fuel Cells

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