terahertz imaging, [9][10][11] terahertz detection, [12][13][14] and so on, terahertz related circuits and electronic components have been widely applied to current technologies. The fast-growing applications for terahertz waves have led to an urgent demand for terahertz shielding materials in order to effectively reduce the interference of terahertz wave signals, improve their transmission environment, and ensure that the delicate electronic instruments work as normal. Moreover, terahertz stealth materials also play a very important role in the fields of national security and information protection, which may help to avoid significant losses to individuals, enterprises, and even countries. Therefore, high-performance terahertz shielding/stealth materials have the potential for wide applications. [15] Traditional terahertz shielding materials are mainly composed of reflective materials because they reflect the incident terahertz wave by simply increasing conductivity. [16,17] For example, it is reported that a terahertz-shielding membrane prepared by a pyrolysis process for commercial polyimide has a very high reflectivity of more than 90%. [18] However, reflective shielding materials have two fatal flaws. First, reflective shielding materials cannot completely eliminate the interference of terahertz waves, because the reflected terahertz wave still adversely affects other sophisticated electronic elements inside the shielded devices. [19] Second, reflective shielding materials usually have a large density. The reflective Strong terahertz-response material which exhibits both excellent terahertz shielding and stealth performance is promising in practical applications of terahertz technology. Here, ultralight graphene foam (GF) and multiwalled carbon nanotubes/multiwalled graphene foam (MGF) have been first demonstrated to achieve both superior terahertz shielding and stealth performance due to the dominant absorption loss with negligible reflection. The terahertz shielding effectiveness values of GF and MGF, both 3 mm thick, reach up to 74 and 61 dB. Meanwhile, their average terahertz reflection loss values are achieved up to 23 and 30 dB, respectively, which are the best results in existing broadband terahertz shielding/stealth materials. Importantly, their qualified absorption bandwidths (reflection loss value larger than 10 dB) cover the entire measured frequency band of 0.1-1.6 THz. Furthermore, the quantitative relationships between the terahertz shielding effectiveness, reflection loss, and material parameters are accurately established, which should facilitate the material design for terahertz shielding and stealth. Comprehensively considering the important indicators of density, bandwidth, and intensity, the specific average terahertz shielding coefficient and the specific average terahertz absorption performance are achieved up to 1.1 × 10 5 and 3.6 × 10 4 dB cm 3 g −1 , respectively, which is over thousands of times larger than other kinds of materials reported previously.
Shielding/Stealth MaterialsThe...