Because of the isomorphism Cl1,3(C) ≅ Cl2,3(R), it is possible to complexify the spacetime Clifford algebra Cl1,3(R) by adding one additional timelike dimension to the Minkowski spacetime. In a recent work we showed how this treatment provide a particular interpretation of Dirac particles and antiparticles in terms of the new temporal dimension. In this article we thoroughly study the structure of the real Clifford algebra Cl2,3(R) paying special attention to the isomorphism Cl1,3(C) ≅ Cl2,3(R) and the embedding Cl1,3(R) ⊆ Cl2,3(R). On the first half of this article we analyze the Pin and Spin groups and construct an injective mapping Pin(1, 3) ↪ Spin(2, 3), obtaining in particular elements in Spin(2, 3) that represent parity and time reversal. On the second half of this paper we study the spinor space of the algebra and prove that the usual structure of complex spinors in Cl1,3(C) is reproduced by the Clifford conjugation inner product for real spinors in Cl2,3(R).