For complex CAD models, model segmentation technology is an important support for model retrieval and reuse. In this article, we first propose a novel CAD model segmentation method that uses the fusion of the program/project evaluation and review technique (PERT) and the Laplacian spectrum theory. By means of PERT, spectral theory, and the CAD models’ geometrical and topological information, we transform the b-rep model faces into two-dimensional coordinate points corresponding to the nodes of the attributed adjacent graph (AAG). The k-means approach with the Silhouette coefficient was employed to conduct unsupervised learning of the coordinate points. The experimental results demonstrate that (1) the proposed approach can effectively transform the b-rep model into a two-dimensional coordinate point set; (2) the k-means algorithm can efficiently cluster points to achieve segmentation; and (3) in view of human cognition, the segmentation results are more reasonable. It can effectively divide the point set into several groups to achieve the model segmentation.