Partial hydrogenation of anisole to cyclohexanone in water medium catalyzed by atomically dispersed Pd anchored in the micropores of zeolite

Xu, Kaiyang; Chen, Yu; Yang, Hua; Gan, Yuyan; Wu, Lizhi; Tan, Li; Dai, Yihu; Tang, Yu

doi:10.1016/j.apcatb.2023.123244

Cited by 7 publications

(1 citation statement)

References 67 publications

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“…Owing to the several advantages of conducting zeolite-catalyzed reactions with water co-feeding or in condensed water phase, a great number of heterogeneous catalytic reactions such as those catalyzed by metal-supported catalysts are being explored increasingly. 5,251–254 Diverse important catalytic transformations can be expanded to be performed with the presence of gaseous water or in aqueous phase. In this context, the green-valorization of biosourced compounds and manufacturing of high-value fine chemicals will be expectedly favored.…”

Section: Discussionmentioning

confidence: 99%

Water structures on acidic zeolites and their roles in catalysis

Liu,

van Bokhoven

2024

Chem. Soc. Rev.

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Section: Discussionmentioning

confidence: 99%

Water structures on acidic zeolites and their roles in catalysis

Liu,

van Bokhoven

2024

Chem. Soc. Rev.

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Building Organic–Inorganic Robust Interphases from Deep Eutectic Solution for Highly Stable Mg Metal Anode in Conventional Electrolyte

Zhou,

Li,

et al. 2023

Small Methods

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Magnesium metal batteries (MMBs) currently face challenges suffering from severe Mg metal passivation and extremely high overpotential in conventional electrolytes. Herein, a strategy of using a low‐cost deep eutectic solution (DES) is proposed to modify Mg anode with the monolithic and compact coating of a MgCl2‐Al‐MgCl2 sandwich structure, enabling the stable and reversible Mg plating–stripping behavior. An organic/nanocrystal hybrid interphase is in‐situ built through a facile Mg‐Al displacement reaction between aluminum‐chloro clusters and Mg in AlCl3/Et3NHCl solution, and it can effectively minimize the adverse interfacial passivation reaction and surface diffusion barrier, affording the high ion‐conduction and electronic insulation. This DES‐assisted method guarantees a highly reversible cycling of Mg metal anode (over 5000 h at 0.1 mA cm−2 and 400 h at 2.0 mAh cm−2) in Mg(TFSI)2/DME electrolyte with the improved interfacial kinetics and low overpotential. Even at a much higher current density of 1 mA cm−2, the overpotential only undergoes a slight increase from 0.2 V (at 0.1 mA cm−2) to 0.23 V. The corresponding full cells with CuS and phenanthraquinone cathodes deliver satisfactory cyclic performance. The DES modification strategy provides a new solution to the design of robust and conductive solid electrolyte interphase for achieving high‐voltage and durable MMBs.

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Hydrogenation of phenol to cyclohexanone catalyzed by isolated Pd cations in the micropores of zeolite

Xu,

Weng,

et al. 2024

Applied Catalysis O: Open

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Partial hydrogenation of anisole to cyclohexanone in water medium catalyzed by atomically dispersed Pd anchored in the micropores of zeolite

Cited by 7 publications

References 67 publications

Water structures on acidic zeolites and their roles in catalysis

Water structures on acidic zeolites and their roles in catalysis

Building Organic–Inorganic Robust Interphases from Deep Eutectic Solution for Highly Stable Mg Metal Anode in Conventional Electrolyte

Hydrogenation of phenol to cyclohexanone catalyzed by isolated Pd cations in the micropores of zeolite

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