In
this work, the behavior of a 200-μm spherical carbon particle
moving in a hot environment mainly consisting of O2 and
CO2 was investigated numerically. The main goal of this
work was to study the influence of the particle velocity, temperature,
and composition of the surrounding gas on the carbon consumption rates.
The particle investigated was placed in a uniform oxygen/carbon dioxide
mixture at different Reynolds numbers corresponding to different laminar
flow regimes. The ambient temperature was systematically varied in
the range of 1000–3000 K, and the mass fraction of O2 was varied between 0.12 and 0.36. To solve the Navier–Stokes
equations for the flow field coupled with the energy and species conservation
equations, a finite volume solver was applied. In addition to the
solid carbon, the model incorporates six gaseous chemical species
(O2, CO, CO2, H2, H2O,
and N2). The semiglobal reaction mechanism includes the
forward and backward water–gas-shift reaction, one reaction
for CO combustion, and four heterogeneous reactions. The ambient medium
was assumed to be nearly dry (Y
H2O = 0.001). The numerical results were carefully validated
against experimental data published in the literature (
Bejarano
Levendis
Bejarano
Levendis
Combust. Flame2008153270287). In particular,
it was shown that taking into account losses from radiation (gas–gas,
gas–solid) brings the results closer to the experimental data.
Additionally, the influence of the gas–gas radiation effect
on the integral characteristics of the oxidizing particle was studied.
In particular, the results are discussed with a focus on the systematic
variation of the ambient-gas temperature and Reynolds number. We found
out that increasing the Reynolds number enhances species transport
to the particle surface and shifts particle oxidation from a diffusion-controlled
to a kinetically controlled regime.