New shape-stabilized paraffin/porous carbon materials derived from metal organic gel (cMOG)/boron nitride (BN) composites were prepared by the impregnation method. In the composites, paraffin was used as phase change material, while cMOG as a supporting and loading large paraffin content in the pores owing to high specific surface area and BN employed to enhance the thermal conductivity. The scanning electron microscopy images showed better filler-filler connectivity in BN/cMOG than the individual supporting materials. With the synergy of BN and cMOG, the thermal conductivity of BN/ cMOG/PCM composites exhibited up to 232.1 % of pristine PCM [a] Beijing