Palladium(II) Complexes with Catecholamines: Synthesis and In Vitro Cytotoxic Activity

Crystal structure of (S)-5-(3-acetyl-5-chloro-2-ethoxy-6-fluorophenyl)-2-oxazolidinone

“…2). In contrast, dichloro-{2-methoxy-4-[2-(pyridin-2-yl)-1,3-oxazolidin-5-yl]phenol}palladium acetonitrile solvate does not show this type of hydrogen bonding, perhaps because the oxazolidinone N atom is also coordinated to palladium (Denisov & Gagarskikh, 2021). Remarkably, the four other structures do display N-H� � �O hydrogen bonding; however, in each case, this leads to pair-wise dimer formation instead of a more extended structure (Chen et al, 2021;Norte et al, 1988;Qin et al, 2012;Bresciani et al, 2020).…”

“…A search of the Cambridge Structural Database with WebCSD (https://www.ccdc.cam.ac.uk/structures/WebCSD, accessed November 8, 2023; Groom et al, 2016) for structures containing the 5-(arene)-oxazolidine-2-one moiety yielded five additional structures: EWIPEI (Chen et al, 2021), GIGHUZ (Norte et al, 1988), MAZDEN (Qin et al, 2012), WAFCEP (Bresciani et al, 2020) and YALYUJ (Denisov & Gagarskikh, 2021).…”