“…As our ongoing research interests in difunctionalizations of alkenes, we recently disclosed several palladium-catalyzed intramolecular amination of alkenes proceeding through 6endo cyclization, giving various 3-substituted piperidines; [15] meanwhile, an asymmetric version has also been achieved by employing a sterically hindered pyridinyl-oxazoline (Pyox) ligand. [16] Notably, for these reactions, the related CÀheter- [*] X. Li, Dr. X. Qi, C. Hou, Dr. P. Chen, Prof. Dr. G. Liu…”