“…To keep the number of experiments reasonable, we elected to screen all reactions with triethylamine as a common base. Three P 2 N 2 ligands with differing phosphine substituents (P Ph , P Cy , and P t Bu ) were chosen for study alongside 9 “gold standard” commercially available phosphine ligands that have been demonstrated to be optimal in related methodologies: dppp, , dppf, ,, JohnPhos, P t Bu 3 , PPh 3 , IMes, DavePhos, 1,10-phenanthroline, and XantPhos . Benzotrifluoroaniline-derived P 2 N 2 ligands were explored, as P 2 Cy N 2 ArCF3 was previously found to be highly effective in nickel-catalyzed cross-couplings. , …”