Palladium‐Catalyzed Cyclization/Alkenylation of Ynone Oximes with Vinylsilanes for the Assembly of Isoxazolyl Vinylsilanes
Jianxiao Li,
Chenjing Hong,
Yanan Niu
et al.
Abstract:A palladium‐catalyzed sequential oxygenation/ vinylation for the assembly of synthetically valuable isoxazolyl vinyl silane derivative has been accomplished. Easily accessible ynone oximes, and readily available vinylsilane agents were used as the reaction starting materials This protocol features broad substrate scope, good functional group tolerance, and good step‐ and atom‐economy. Remarkably, this approach provides a new channel for the construction of structurally diverse isoxazolyl‐containing vinylsilane… Show more
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