Palladium‐Catalyzed Cross‐Coupling of Aryl Thioacetates and Chloro(hetero)arenes

Zhao, Tan; Liang, Feng; Cai, Mingjun; Chen, Junling; Kang, Chuanqing; Wang, Hongda; Wu, Qiang

doi:10.1002/ajoc.202000025

Cited by 4 publications

(1 citation statement)

References 50 publications

(18 reference statements)

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“…Aryl(heteroaryl) chlorides react in a Pd/XPhos catalytic system when using KOtBu as a base (Scheme 28, A). 211 The reaction did not proceed with aliphatic sulfur derivatives.…”

Section: Catalytic Cross-coupling Reactions (mentioning

confidence: 99%

Transition-Metal-Catalyzed C–S, C–Se, and C–Te Bond Formations via Cross-Coupling and Atom-Economic Addition Reactions. Achievements and Challenges

2022

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In the present review, we discuss recent progress in the field of C–Z bond formation reactions (Z = S, Se, Te) catalyzed by transition metals. Two complementary methodologies are consideredcatalytic cross-coupling reactions and catalytic addition reactions. The development of advanced catalytic systems is aimed at improved catalyst efficiency, reduced catalyst loading, better cost efficiency, environmental concerns, and higher selectivity and yields. The important rise of research efforts in sustainability and green chemistry areas is critically assessed. The paramount role of mechanistic studies in the development of a new generation of catalytic systems is addressed, and the key achievements, problems, and challenges are summarized for this field.

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“…Aryl(heteroaryl) chlorides react in a Pd/XPhos catalytic system when using KOtBu as a base (Scheme 28, A). 211 The reaction did not proceed with aliphatic sulfur derivatives.…”

Section: Catalytic Cross-coupling Reactions (mentioning

confidence: 99%

Transition-Metal-Catalyzed C–S, C–Se, and C–Te Bond Formations via Cross-Coupling and Atom-Economic Addition Reactions. Achievements and Challenges

2022

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One-pot synthesis of 11-sulfenyl dibenzodiazepinesviatandem sulfenylation/cyclization ofo-isocyanodiaryl amines and diaryl disulfides

et al. 2023

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Recent Metal-Catalyzed Methods for Thioether Synthesis

et al. 2022

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This review summarizes the more recent methods for the synthesis of thioethers using homogeneous metals as catalysts. The thioether moiety can be found in numerous compounds for pharmaceutical, agricultural or material applications and it is therefore important to develop new, efficient methods for their synthesis. The recent efforts in this field focus on the use of non-precious metal catalysts, as well as on the development of new bond-forming processes. 1 Introduction 2 Cross-couplings 3 C-H Activation 4 Hydrothiolation 5 Carbothiolation 6 Miscelaneous 7 Conclusion

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Palladium‐Catalyzed Cross‐Coupling of Aryl Thioacetates and Chloro(hetero)arenes

Cited by 4 publications

References 50 publications

Transition-Metal-Catalyzed C–S, C–Se, and C–Te Bond Formations via Cross-Coupling and Atom-Economic Addition Reactions. Achievements and Challenges

Transition-Metal-Catalyzed C–S, C–Se, and C–Te Bond Formations via Cross-Coupling and Atom-Economic Addition Reactions. Achievements and Challenges

One-pot synthesis of 11-sulfenyl dibenzodiazepinesviatandem sulfenylation/cyclization ofo-isocyanodiaryl amines and diaryl disulfides

Recent Metal-Catalyzed Methods for Thioether Synthesis

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