Nanoporous Pt/TiO 2 micro-particles were synthesized via an aerosol assisted co-assembly (AACA) route. Aerosol droplets were produced from a colloidal mixture of 5 nm Pt and 20 nm TiO 2 nanoparticles, which formed spherical micro-aggregates of Pt and TiO 2 with average diameter of around 1.2 µm. The resulting composite micro-particles have very open structure with pore sizes ranging from 20 to 200 nm. Pt nanoparticles were found to be well dispersed on the surface of the supporting TiO 2 particles. Electrocatalytic application of the nanoporous Pt/TiO 2 composites was examined through methanol oxidation reaction. The performance of 20 wt% Pt/TiO 2 particles was found to be comparable to that of commercial 20 wt% Pt/carbon black catalyst.