2021
DOI: 10.1115/1.0001374v
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Oxygen Crossover in Solid-Solid Heat Exchangers for Solar Water and Carbon Dioxide Splitting: A Thermodynamic Analysis

Abstract: In solar thermochemical redox cycles for H 2 O/CO 2 -splitting, a large portion of the overall energy demand of the system is associated with heating the redox material from the oxidation temperature to the reduction temperature. Hence, an important measure to improve the efficiency is recuperation of sensible heat stored in the redox material. A solid-solid heat exchanger can be subjected to undesirable oxygen crossover, which decreases the oxygen uptake capacity of the redox material and consequently the sys… Show more

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