“…Indeed, functionalization of hydrazines is often challenging due to the toxicity, hazardous, and air sensitive character of many reagents. There is also an inherent chemoselectivity issue arising from the two reactive nucleophilic nitrogen atoms. , Additionally, the formation of N–N bonds often involves hazardous reactions (e.g., nitrosation or nitration) or a prefunctionalization to perform the cleavage of weak N–X bonds (where X = O, N, or Cl in the Raschig–Olin process) . Aza-Favorskii reactions of N-monosubstituted ureas was also reported to form hydrazine derivatives following ring opening of the diaziridone intermediate. , Many N–N bonds have been formed via dimerization, , but typically, the formation of heterodimers is difficult.…”