Oxidative esterification of alcohols and aldehydes using supported iron oxide nanoparticle catalysts

Rajabi, Fatemeh; Arancon, Rick Arneil D.; Luque, Rafael

doi:10.1016/j.catcom.2014.09.022

Cited by 27 publications

(10 citation statements)

References 21 publications

(28 reference statements)

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“…We have previously reported in our earlier papers about the catalytic performance of FeNP@SBA-15 in various types of organic transformations including oxidation of sulfides to sulfoxides [44], esterification of carboxylic acids [45], oxidation of styrene derivatives [46] and oxidative esterification of alcohols and aldehydes (Table S1) [47]. The results of the mentioned reports confirmed the high catalytic activities of supported FeNP in different conditions.…”

Section: Resultssupporting

confidence: 62%

Solvent-Free Preparation of 1,8-Dioxo-Octahydroxanthenes Employing Iron Oxide Nanomaterials

et al. 2019

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In this study, 1,8-dioxo-octahydroxanthenes were prepared employing a simple, effective and environmentally sound approach utilizing an iron oxide nanocatalyst under solventless conditions. The proposed iron oxide nanomaterial exhibited high product yields, short reaction times and a facile work-up procedure. The synthesized catalyst was also found to be highly stable and reusable under the investigated conditions (up to twelve consecutive cycles) without any significant loss in its catalytic activity.

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Section: Resultssupporting

confidence: 62%

Solvent-Free Preparation of 1,8-Dioxo-Octahydroxanthenes Employing Iron Oxide Nanomaterials

et al. 2019

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“…In continuation of our previous study on the application of FeNP@SBA-15 as a recoverable catalyst [26], we found that the esterification of carboxylic acids in the presence of FeNP@SBA-15 as an effective catalyst has not been investigated yet. Hence, we decided to investigate the catalytic effect of FeNP@SBA-15 as a promoter system on the rate and efficiency of esterification of carboxylic acids.…”

Section: Resultsmentioning

confidence: 94%

Solvent-Free Esterification of Carboxylic Acids Using Supported Iron Oxide Nanoparticles as an Efficient and Recoverable Catalyst

2016

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Supported iron oxide nanoparticles on mesoporous materials (FeNP@SBA-15) have been successfully utilized in the esterification of a variety carboxylic acids including aromatic, aliphatic, and long-chain carboxylic acids under convenient reaction conditions. The supported catalyst could be easily recovered after reaction completion and reused several times without any loss in activity after up to 10 runs.

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“…Magnetic iron oxide nanoparticles (NPs), such as magnetite (Fe 3 O 4 ) and maghemite (γ-Fe 2 O 3 ), have been found and applied in a wide range of biomedical applications [1,2,3,4,5,6,7,8,9], including magnetic resonance imaging, magnetic hyperthermia, cancer therapy, and drug delivery; they also find applications in catalysis [10,11,12] and in magnetic separation [13,14]. Among other metal nanoparticles, iron oxide nanoparticles have been more extensively studied in clinical practice [15].…”

Section: Introductionmentioning

confidence: 99%

Fe3O4 Nanoparticles for Complex Targeted Delivery and Boron Neutron Capture Therapy

et al. 2019

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Magnetic Fe3O4 nanoparticles (NPs) and their surface modification with therapeutic substances are of great interest, especially drug delivery for cancer therapy, including boron-neutron capture therapy (BNCT). In this paper, we present the results of boron-rich compound (carborane borate) attachment to previously aminated by (3-aminopropyl)-trimethoxysilane (APTMS) iron oxide NPs. Fourier transform infrared spectroscopy with Attenuated total reflectance accessory (ATR-FTIR) and energy-dispersive X-ray analysis confirmed the change of the element content of NPs after modification and formation of new bonds between Fe3O4 NPs and the attached molecules. Transmission (TEM) and scanning electron microscopy (SEM) showed Fe3O4 NPs’ average size of 18.9 nm. Phase parameters were studied by powder X-ray diffraction (XRD), and the magnetic behavior of Fe3O4 NPs was elucidated by Mössbauer spectroscopy. The colloidal and chemical stability of NPs was studied using simulated body fluid (phosphate buffer—PBS). Modified NPs have shown excellent stability in PBS (pH = 7.4), characterized by XRD, Mössbauer spectroscopy, and dynamic light scattering (DLS). Biocompatibility was evaluated in-vitro using cultured mouse embryonic fibroblasts (MEFs). The results show us an increasing of IC50 from 0.110 mg/mL for Fe3O4 NPs to 0.405 mg/mL for Fe3O4-Carborane NPs. The obtained data confirm the biocompatibility and stability of synthesized NPs and the potential to use them in BNCT.

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Oxidative esterification of alcohols and aldehydes using supported iron oxide nanoparticle catalysts

Cited by 27 publications

References 21 publications

Solvent-Free Preparation of 1,8-Dioxo-Octahydroxanthenes Employing Iron Oxide Nanomaterials

Solvent-Free Preparation of 1,8-Dioxo-Octahydroxanthenes Employing Iron Oxide Nanomaterials

Solvent-Free Esterification of Carboxylic Acids Using Supported Iron Oxide Nanoparticles as an Efficient and Recoverable Catalyst

Fe3O4 Nanoparticles for Complex Targeted Delivery and Boron Neutron Capture Therapy

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