Oxidative Corrosion Mechanism of Ti2AlNb-Based Alloys during Alternate High Temperature-Salt Spray Exposure

Abstract

This study investigates the corrosion damage mechanisms of Ti2AlNb-based alloys under high temperature, salt spray and coupled high temperature-salt spray conditions. This alloy was analysed in detail from macroscopic to microscopic by means of microscale detection (XRD, SEM and EDS). The results indicated that Ti2AlNb-based alloy surface oxide layer is dense and complete, and the thickness is only 3 µm after oxidation at 650 °C for 400 h. Compared to the original sample, the production of the passivation film resulted in almost no damage to Ti2AlNb-based alloy after 50 cycles of salt spray testing at room temperature. The tests showed that Ti2AlNb alloy shows good erosion resistance at 650 °C and in salt spray. However, this alloy had an oxide layer thickness of up to 30 µm and obvious corrosion pits on the surface after 50 cycles of corrosion under alternating high temperature-salt spray conditions. The Cl2 produced by the mixed salt eutectic reaction acted as a catalytic carrier to accelerate the volatilisation of the chloride inside the oxide layer and the re-oxidation of the substrate. In addition, the growth of unprotected corrosion products (Na2TiO3, NaNbO3 and AlNbO4) altered the internal structure of the oxide layer, destroying the surface densification and causing severe damage to the alloy surface.

First-Principles Investigation on the Adsorption and Diffusion of Oxygen at the B2(110)–O(001) Interface in Ti2AlNb Alloys

“…Ti 2 AlNb alloys are composed of an order of the orthorhombic (O) phase (space group: Cmcm, Pearson symbol: oS16), B2 phase (space group: Pm3m, Pearson symbol: cP2), and α 2 phase (space group: P6 3 /mmc, Pearson symbol: hP8) [4,5]. As a hightemperature alloy, the oxidation resistance of Ti 2 AlNb alloy is not good above 750 • C [6][7][8]. This is because the competitive oxidation of Ti and Al occurs at high temperatures, failing to produce a dense oxide layer to protect the alloy matrix [9,10].…”